Ions in Solution: Basic Principles of Chemical InteractionsElsevier, 01.10.1999 - 240 Seiten This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding.
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Inhalt
| 9 | |
| 11 | |
| 15 | |
Chapter 2 Solvation numbers | 28 |
Chapter 3 Ionsolvent distances | 36 |
Chapter 4 Ionsolvent interactions | 45 |
Chapter 5 Acidbase behaviour hydrolysis and polymerisation | 62 |
Chapter 6 Stability constants | 74 |
solvent exchange | 111 |
complex formation | 124 |
substitution at complex ions | 146 |
redox reactions | 153 |
Chapter 13 Past present and future | 170 |
Glossary | 176 |
Further reading | 183 |
Exercises problems and projects | 193 |
Andere Ausgaben - Alle anzeigen
Ions in Solution: Basic Principles of Chemical Interactions J Burgess Keine Leseprobe verfügbar - 1999 |
Häufige Begriffe und Wortgruppen
acid activation entropies activation volumes alkali metal alkali metal cations anion aqua-ions aqua-metal aquacations aqueous solution atoms bond cations Chapter chelate chelate ring Chem chloride chromium(III cobalt(III complex formation concentration copper(II Cr3+ crown ethers cryptand Crystal Field Cu2+ cyanide d-block dissociative effect electron transfer equilibrium constants estimate example formation reactions give hydration enthalpies hydration numbers hydrolysis inner-sphere interactions ion solvation ion-solvent ions in solution iron(III kinetics and mechanisms kJ mol logio macrocyclic metal complexes metal ions methanol molar moldm Ni2+ octahedral outer-sphere oxidation oxoanions perchlorate Periodic Table platinum(II polynuclear primary hydration primary solvation shell proton radial distribution functions radius range rate constants rate law reactivity redox potentials redox reactions salt shown in Fig solubility solution chemistry solvation numbers solvation shell solvent solvent exchange solvent molecules species spectra spectroscopy stabilisation stability constants substitution thermodynamic transition metal values water exchange water molecules Zn2+